75.81—Monitoring of Hg mass emissions and heat input at the unit level.

The owner or operator of the affected coal-fired unit shall either:
(a) Meet the general operating requirements in § 75.10 for the following continuous emission monitors (except as provided in accordance with subpart E of this part):
(1) A Hg concentration monitoring system (as defined in § 72.2 of this chapter) or a sorbent trap monitoring system (as defined in § 72.2 of this chapter ), to measure the mass concentration of total vapor phase Hg in the flue gas, including the elemental and oxidized forms of Hg, in micrograms per standard cubic meter (µg/scm); and
(3) A continuous moisture monitoring system (if correction of Hg concentration for moisture is required), as described in § 75.11(b). Alternatively, the owner or operator may use the appropriate fuel-specific default moisture value provided in § 75.11, or a site-specific moisture value approved by petition under § 75.66; and
(b) For an affected unit that emits 464 ounces (29 lb) of Hg per year or less, use the following excepted monitoring methodology. To implement this methodology for a qualifying unit, the owner or operator shall meet the general operating requirements in § 75.10 for the continuous emission monitors described in paragraphs (a)(2) and (a)(4) of this section, and perform Hg emission testing for initial certification and on-going quality-assurance, as described in paragraphs (c) through (e) of this section.
(1) The owner or operator must perform Hg emission testing one year or less before the compliance date in § 75.80(b), to determine the Hg concentration (i.e., total vapor phase Hg) in the effluent.
(i) The testing shall be performed using one of the Hg reference methods listed in § 75.22(a)(7), and shall consist of a minimum of 3 runs at the normal unit operating load, while combusting coal. The coal combusted during the testing shall be representative of the coal that will be combusted at the start of the Hg mass emissions reduction program (preferably from the same source(s) of supply).
(ii) The minimum time per run shall be 1 hour if Method 30A is used. If either Method 29 in appendix A-8 to part 60 of this chapter, ASTM D6784-02 (the Ontario Hydro method) (incorporated by reference under § 75.6 of this part ), or Method 30B is used, paired samples are required for each test run and the runs must be long enough to ensure that sufficient Hg is collected to analyze. When Method 29 in appendix A-8 to part 60 of this chapter or the Ontario Hydro method is used, the test results shall be based on the vapor phase Hg collected in the back-half of the sampling trains (i.e., the non-filterable impinger catches). For each Method 29 in appendix A-8 to part 60 of this chapter, Method 30B, or Ontario Hydro method test run, the paired trains must meet the relative deviation (RD) requirement specified in § 75.22(a)(7) or Method 30B, as applicable. If the RD specification is met, the results of the two samples shall be averaged arithmetically.
(iv) If two or more of units of the same type qualify as a group of identical units in accordance with § 75.19(c)(1)(iv)(B), the owner or operator may test a subset of these units in lieu of testing each unit individually. If this option is selected, the number of units required to be tested shall be determined from Table LM-4 in § 75.19. For the purposes of the required retests under paragraph (d)(4) of this section, EPA strongly recommends that (to the extent practicable) the same subset of the units not be tested in two successive retests, and that every effort be made to ensure that each unit in the group of identical units is tested in a timely manner.

Code of Federal Regulations

[Please see PDF for image: ER24JA08.018 ]
Where:
E = Estimated annual Hg mass emissions from the affected unit, (ounces/year)
K = Units conversion constant, 9.978 x 10−10 oz-scm/µg-scf
N = Either 8,760 (the number of hours in a year) or the maximum number of operating hours per year (if less than 8,760) allowed by the unit's Federally-enforceable operating permit.
CHg = The highest Hg concentration (µg/scm) from any of the test runs or 0.50 µg/scm, whichever is greater
Qmax = Maximum potential flow rate, determined according to section 2.1.4.1 of appendix A to this part, (scfh)
(iv) An additional retest is required when there is a change in the coal rank of the primary fuel (e.g., when the primary fuel is switched from bituminous coal to lignite). Use ASTM D388-99 (incorporated by reference under § 75.6 of this part) to determine the coal rank. The four principal coal ranks are anthracitic, bituminous, subbituminous, and lignitic. The ranks of anthracite coal refuse (culm) and bituminous coal refuse (gob) shall be anthracitic and bituminous, respectively. The retest shall be performed within 720 unit operating hours of the change.
(5) The default Hg concentration used for reporting under § 75.84 shall be updated after each required retest. This includes retests that are required prior to the compliance date in § 75.80(b). The updated value shall either be the highest Hg concentration measured in any of the test runs or 0.50 µg/scm, whichever is greater. The updated value shall be applied beginning with the first unit operating hour in which Hg emissions data are required to be reported after completion of the retest, except as provided in paragraph (d)(4)(iv) of this section, where the need to retest is triggered by a change in the coal rank of the primary fuel. In that case, apply the updated default Hg concentration beginning with the first unit operating hour in which Hg emissions are required to be reported after the date and hour of the fuel switch.
(6) If the unit is equipped with a flue gas desulfurization system or add-on Hg controls, the owner or operator shall record the information required under § 75.58(b)(3) for each unit operating hour, to document proper operation of the emission controls. For any operating hour in which this documentation is unavailable, the maximum potential Hg concentration, as defined in section 2.1.7 of appendix A to this part, shall be reported.
(ii) The retests required under paragraph (d)(4) of this section may also be done at the common stack. If this testing option is chosen, the testing shall be done at a combined load corresponding to the designated normal load level (low, mid, or high) for the units sharing the common stack, in accordance with section 6.5.2.1 of appendix A to this part. Provided that the required load level is attained and that all of the units sharing the stack are fed from the same on-site coal supply during normal operation, it is not necessary for all of the units sharing the stack to be in operation during a retest. However, if two or more of the units that share the stack are fed from different on-site coal supplies (e.g., one unit burns low-sulfur coal for compliance and the other combusts higher-sulfur coal), then either:
(g) For an affected unit that is using a Hg concentration CEMS or a sorbent trap system under § 75.81(a) to continuously monitor the Hg mass emissions, the owner or operator may switch to the methodology in § 75.81(b), provided that the applicable conditions in paragraphs (c) through (f) of this section are met.
[70 FR 28684, May 18, 2005, as amended at 72 FR 51528, Sept. 7, 2007; 73 FR 4360, Jan. 24, 2008]