CFR > Title 49 - Transportation > SUBTITLE B—Other Regulations Relating to Transportation > CHAPTER I—PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (Parts 105–199) > SUBCHAPTER C—HAZARDOUS MATERIALS REGULATIONS (Parts 171–181) > PART 176—CARRIAGE BY VESSEL > SUBPART G—Detailed Requirements for Class 1 (Explosive) Materials (§176.100 to §176.194) > 176.142—Hazardous materials of extreme flammability.

176.142—Hazardous materials of extreme flammability.

(a) Except as allowed by paragraph (b) of this section, certain hazardous materials of extreme flammability may not be transported in a vessel carrying Class 1 (explosive) materials. This prohibition applies to the following liquid hazardous materials:
Carbon disulfide UN1131 Class 3
Diethylzinc UN1366 Division 4.2
Dimethylzinc UN1370 Division 4.2
Magnesium alkys UN3053 Division 4.2
Methyl phosphonous di-chloride, pyrophoric liquid. NA2845 Division 6.1
Nickel carbonyl UN1259 Division 6.1
Pyrophoric liquid, inorganic, n.o.s. UN3194 Division 4.2
Pyrophoric liquid, organic, n.o.s. UN2845 Division 4.2
Code of Federal Regulations 773
Organometallic substance, liquid, pyrophoric. UN3392 Division 4.2
Organometallic substance, liquid, pyrophoric, water-reactive. UN3394 Division 4.2
(b) The hazardous materials listed in paragraph (a) of this section may be transported in a vessel carrying the following Class 1 (explosive) materials as cargo:
(1) Division 1.4 (explosive) materials, compatibility group S.
(2) Explosive articles having the following proper shipping names and identification numbers (see column (4) of the § 172.101 table) if designed for lifesaving purposes and their total net explosive mass (weight) does not exceed 50 kg (110 lbs) per vessel:
(i) ARTICLES, PYROTECHNIC: UN Nos. 0428, 0429, 0430, 0431.
(ii) CARTRIDGES, FLASH: UN Nos. 0049, 0050.
(iii) CARTRIDGES, SIGNAL: UN Nos. 0054, 0312.
(iv) SIGNAL DEVICES, HAND: UN No. 0191.
(v) SIGNALS, DISTRESS: UN Nos. 0194, 0195.
(vi) SIGNALS, SMOKE: UN Nos. 0196, 0197, 0313.
(3) Class 1 (explosive) materials in compatibility groups C, D, and E if the total net explosive mass (weight) does not exceed 10 kg (22 pounds) per vessel.
(4) Explosive articles in compatibility group G, except fireworks and Class 1 (explosive) materials requiring special stowage if the total net explosive mass (weight) does not exceed 10 kg (22 pounds) per vessel.
(c) When a vessel carrying Class 1 (explosive) materials allowed under paragraph (b) of this section also carries a hazardous material of extreme flammability, that hazardous material must be stowed in a part of the vessel as remote as practicable from the Class 1 (explosive) materials.
[Amdt. 176-30, 55 FR 52696, Dec. 21, 1990, as amended at 66 FR 33438, June 21, 2001; 66 FR 45384, Aug. 28, 2001; 69 FR 76184, Dec. 20, 2004]