173.225—Packaging requirements and other provisions for organic peroxides.
(a) General.
When the § 172.101 table specifies that an organic peroxide must be packaged under this section, the organic peroxide must be packaged and offered for transportation in accordance with the provisions of this section. Each packaging must conform to the general requirements of subpart B of part 173 and to the applicable requirements of part 178 of this subchapter. Non-bulk packagings must meet Packing Group II performance levels. To avoid unnecessary confinement, metallic non-bulk packagings meeting Packing Group I are not authorized. No used material, other than production residues or regrind from the same production process, may be used in plastic packagings. Organic peroxides that require temperature control are subject to the provisions of § 173.21(f). When an IBC or bulk packaging is authorized and meets the requirements of paragraph (f) or (h) of this section, respectively, lower control temperatures than those specified for non-bulk packaging may be required. An organic peroxide not identified in paragraph (c), (e), or (g) of this section by technical name, or not assigned to a generic type in accordance with the provisions in paragraph (b)(3) of this section, must conform to the provisions of paragraph (c) of § 173.128.
(b) New organic peroxides, formulations and samples.
(1)
Except as provided for samples in paragraph (b)(2) of this section, no person may offer for transportation an organic peroxide that is not identified by technical name in the Organic Peroxides Table, Organic Peroxide IBC Table, or the Organic Peroxide Portable Tank Table of this section, or a formulation of one or more organic peroxides that are identified by technical name in one of those tables, unless the organic peroxide is assigned a generic type and shipping description and is approved by the Associate Administrator under the provisions of § 173.128(d) of this subchapter.
(2) Samples.
Samples of new organic peroxides or new formulations of organic peroxides identified in the Organic Peroxides Table in paragraph (c) of this section, for which complete test data are not available, and that are to be transported for further testing or product evaluation, may be assigned an appropriate shipping description for organic peroxide Type C, packaged and offered for transportation, under the following conditions:
(i)
Data available to the person offering the material for transportation must indicate that the sample would pose a level of hazard no greater than that of an organic peroxide Type B and that the control temperature, if any, is sufficiently low to prevent any dangerous decomposition and sufficiently high to prevent any dangerous phase separation;
(ii)
The sample must be packaged in accordance with packing method OP2, for a liquid or solid, respectively;
(iii)
Packages of the organic peroxide may be offered for transportation and transported in a quantity not to exceed 10 kg (22 pounds) per transport vehicle; and
(3) Mixtures.
Mixtures of organic peroxides individually identified in the Organic Peroxides Table in paragraph (c) of this section may be classified as the same type of organic peroxide as that of the most dangerous component and be transported under the conditions for transportation given for this type. If the stable components form a thermally less stable mixture, the SADT of the mixture must be determined and the new control and emergency temperature derived under the provisions of § 173.21(f).
(c) Organic peroxides table.
The following Organic Peroxides Table specifies by technical name those organic peroxides that are authorized for transportation and not subject to the approval provisions of § 173.128 of this part. An organic peroxide identified by technical name in the following table is authorized for transportation only if it conforms to all applicable provisions of the table. The column headings of the Organic Peroxides Table are as follows:
(2) ID number.
The second column specifies the identification (ID) number which is used to identify the proper shipping name in the § 172.101 table. The word “EXEMPT” appearing in the column denotes that the material is not regulated as an organic peroxide.
(3) Concentration of organic peroxide.
The third column specifies concentration (mass percent) limitations, if any, in mixtures or solutions for the organic peroxide. Limitations are given as minimums, maximums, or a range, as appropriate. A range includes the lower and upper limits (i.e., “53-100” means from, and including, 53% to, and including 100%). See introductory paragraph of § 172.203(k) of this subchapter for additional description requirements for an organic peroxide that may qualify for more than one generic listing, depending on its concentration.
(4) Concentration of diluents.
The fourth column specifies the type and concentration (mass percent) of diluent or inert solid, when required. Other types and concentrations of diluents may be used if approved by the Associate Administrator.
(i)
The required mass percent of “Diluent type A” is specified in column 4a. A diluent type A is an organic liquid that does not detrimentally affect the thermal stability or increase the hazard of the organic peroxide and with a boiling point not less than 150 °C at atmospheric pressure. Type A diluents may be used for desensitizing all organic peroxides.
(ii)
The required mass percent of “Diluent type B” is specified in column 4b. A diluent type B is an organic liquid which is compatible with the organic peroxide and which has a boiling point, at atmospheric pressure, of less than 150 °C (302 °F) but at least 60 °C (140 °F), and a flash point greater than 5 °C (41 °F). Type B diluents may be used for desensitizing all organic peroxides, when specified in the organic peroxide tables, provided that the boiling point is at least 60 °C (140 °F) above the SADT of the peroxide in a 50 kg (110 lbs) package. A type A diluent may be used to replace a type B diluent in equal concentration.
(iii)
The required mass percent of “Inert solid” is specified in column 4c. An inert solid is a solid that does not detrimentally affect the thermal stability or hazard of the organic peroxide.
(5) Concentration of water.
Column 5 specifies, in mass percent, the minimum amount of water, if any, which must be in formulation.
(6) Packing method.
Column 6 specifies the highest packing method (largest packaging capacity) authorized for the organic peroxide. Lower numbered packing methods (smaller packaging capacities) are also authorized. For example, if OP3 is specified, then OP2 and OP1 are also authorized. The Table of Packing Methods in paragraph (d) of this section defines the non-bulk packing methods.
(7) Temperatures.
Column 7a specifies the control temperature. Column 7b specifies the emergency temperature. Temperatures are specified only when temperature controls are required. (See § 173.21(f) ).
(8) Notes.
Column 8 specifies other applicable provisions, as set forth in notes following the table.
Technical name | ID number | Concentration (mass %) | Diluent (mass %) | Water (mass %) | Packing method | Temperature ( °C) | Notes | |||
---|---|---|---|---|---|---|---|---|---|---|
A | B | I | Control | Emergency | ||||||
(1) | (2) | (3) | (4a) | (4b) | (4c) | (5) | (6) | (7a) | (7b) | (8) |
Acetyl acetone peroxide | UN3105 | ≤42 | ≥48 | ≥8 | OP7 | 2 | ||||
Acetyl acetone peroxide [as a paste] | UN3106 | ≤32 | OP7 | 21 | ||||||
Acetyl cyclohexanesulfonyl peroxide | UN3112 | ≤82 | ≥12 | OP4 | −10 | 0 | ||||
Acetyl cyclohexanesulfonyl peroxide | UN3115 | ≤32 | ≥68 | OP7 | −10 | 0 | ||||
tert-Amyl hydroperoxide | UN3107 | ≤88 | ≥6 | ≥6 | OP8 | |||||
tert-Amyl peroxyacetate | UN3105 | ≤62 | ≥38 | OP7 | ||||||
tert-Amyl peroxybenzoate | UN3103 | ≤100 | OP5 | |||||||
tert-Amyl peroxy-2-ethylhexanoate | UN3115 | ≤100 | OP7 | 20 | 25 | |||||
tert-Amyl peroxy-2-ethylhexyl carbonate | UN3105 | ≤100 | OP7 | |||||||
tert-Amyl peroxy isopropyl carbonate | UN3103 | ≤77 | ≥23 | OP5 | ||||||
tert-Amyl peroxyneodecanoate | UN3115 | ≤77 | ≥23 | OP7 | 0 | 10 | ||||
tert-Amyl peroxyneodecanoate | 3119 | ≤47 | ≥53 | OP8 | 0 | 10 | ||||
tert-Amyl peroxypivalate | UN3113 | ≤77 | ≥23 | OP5 | 10 | 15 | ||||
tert-Amyl peroxypivalate | 3119 | ≤32 | ≥68 | OP8 | 10 | 15 | ||||
tert-Amyl peroxy-3,5,5-trimethylhexanoate | 3105 | ≤100 | OP7 | |||||||
tert-Butyl cumyl peroxide | UN3107 | >42-100 | OP8 | 9 | ||||||
tert-Butyl cumyl peroxide | UN3108 | ≤52 | ≥48 | OP8 | 9 | |||||
n-Butyl-4,4-di-(tert-butylperoxy)valerate | UN3103 | >52-100 | OP5 | |||||||
n-Butyl-4,4-di-(tert-butylperoxy)valerate | UN3108 | ≤52 | ≥48 | OP8 | ||||||
tert-Butyl hydroperoxide | UN3103 | >79-90 | ≥10 | OP5 | 13 | |||||
tert-Butyl hydroperoxide | UN3105 | ≤80 | ≥20 | OP7 | 4, 13 | |||||
tert-Butyl hydroperoxide | UN3107 | ≤79 | >14 | OP8 | 13, 16 | |||||
tert-Butyl hydroperoxide | UN3109 | ≤72 | ≥28 | OP8 | 13 | |||||
tert-Butyl hydroperoxide [and] Di-tert-butylperoxide | UN3103 | <82 >9 | ≥7 | OP5 | 13 | |||||
tert-Butyl monoperoxymaleate | UN3102 | >52-100 | OP5 | |||||||
tert-Butyl monoperoxymaleate | UN3103 | ≤52 | ≥48 | OP6 | ||||||
tert-Butyl monoperoxymaleate | UN3108 | ≤52 | ≥48 | OP8 | ||||||
tert-Butyl monoperoxymaleate [as a paste] | UN3108 | ≤52 | OP8 | |||||||
tert-Butyl peroxyacetate | UN3101 | >52-77 | ≥23 | OP5 | ||||||
tert-Butyl peroxyacetate | UN3103 | >32-52 | ≥48 | OP6 | ||||||
tert-Butyl peroxyacetate | UN3109 | ≤32 | ≥68 | OP8 | ||||||
tert-Butyl peroxybenzoate | UN3103 | >77-100 | OP5 | |||||||
tert-Butyl peroxybenzoate | UN3105 | >52-77 | ≥23 | OP7 | 1 | |||||
tert-Butyl peroxybenzoate | UN3106 | ≤52 | ≥48 | OP7 | ||||||
tert-Butyl peroxybenzoate | 3109 | ≤32 | ≥68 | OP8 | ||||||
tert-Butyl peroxybutyl fumarate | UN3105 | ≤52 | ≥48 | OP7 | ||||||
tert-Butyl peroxycrotonate | UN3105 | ≤77 | ≥23 | OP7 | ||||||
tert-Butyl peroxydiethylacetate | UN3113 | ≤100 | OP5 | 20 | 25 | |||||
tert-Butyl peroxy-2-ethylhexanoate | UN3113 | >52-100 | OP6 | 20 | 25 | |||||
tert-Butyl peroxy-2-ethylhexanoate | UN3117 | >32-52 | ≥48 | OP8 | 30 | 35 | ||||
tert-Butyl peroxy-2-ethylhexanoate | UN3118 | ≤52 | ≥48 | OP8 | 20 | 25 | ||||
tert-Butyl peroxy-2-ethylhexanoate | UN3119 | ≤32 | ≥68 | OP8 | 40 | 45 | ||||
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tert-Butyl peroxy-2-ethylhexanoate [and] 2,2-di-(tert-Butylperoxy)butane | UN3106 | ≤12 ≤14 | ≥14 | ≥60 | OP7 | |||||
tert-Butyl peroxy-2-ethylhexanoate [and] 2,2-di-(tert-Butylperoxy)butane | UN3115 | ≤31 ≤36 | ≥33 | OP7 | 35 | 40 | ||||
tert-Butyl peroxy-2-ethylhexylcarbonate | UN3105 | ≤100 | OP7 | |||||||
tert-Butyl peroxyisobutyrate | UN3111 | >52-77 | ≥23 | OP5 | 15 | 20 | ||||
tert-Butyl peroxyisobutyrate | UN3115 | ≤52 | ≥48 | OP7 | 15 | 20 | ||||
tert-Butylperoxy isopropylcarbonate | UN3103 | ≤77 | ≥23 | OP5 | ||||||
1-(2-tert-Butylperoxy isopropyl)-3-isopropenylbenzene | UN3105 | ≤77 | ≥23 | OP7 | ||||||
1-(2-tert-Butylperoxy isopropyl)-3-isopropenylbenzene | UN3108 | ≤42 | ≥58 | OP8 | ||||||
tert-Butyl peroxy-2-methylbenzoate | UN3103 | ≤100 | OP5 | |||||||
tert-Butyl peroxyneodecanoate | UN3115 | >77-100 | OP7 | −5 | 5 | |||||
tert-Butyl peroxyneodecanoate | UN3115 | ≤77 | ≥23 | OP7 | 0 | 10 | ||||
tert-Butyl peroxyneodecanoate [as a stable dispersion in water] | UN3119 | ≤52 | OP8 | 0 | 10 | |||||
tert-Butyl peroxyneodecanoate [as a stable dispersion in water (frozen)] | UN3118 | ≤42 | OP8 | 0 | 10 | |||||
tert-Butyl peroxyneodecanoate | UN3119 | ≤32 | ≥68 | OP8 | 0 | 10 | ||||
tert-Butyl peroxyneoheptanoate | UN3115 | ≤77 | ≥23 | OP7 | 0 | 10 | ||||
tert-Butyl peroxyneoheptanoate [as a stable dispersion in water] | UN3117 | ≤42 | OP8 | 0 | 10 | |||||
tert-Butyl peroxypivalate | UN3113 | >67-77 | ≥23 | OP5 | 0 | 10 | ||||
tert-Butyl peroxypivalate | UN3115 | >27-67 | ≥33 | OP7 | 0 | 10 | ||||
tert-Butyl peroxypivalate | UN3119 | ≤27 | ≥73 | OP8 | 30 | 35 | ||||
tert-Butylperoxy stearylcarbonate | UN3106 | ≤100 | OP7 | |||||||
tert-Butyl peroxy-3,5,5-trimethylhexanoate | UN3105 | >32-100 | OP7 | |||||||
tert-Butyl peroxy-3,5,5-trimethlyhexanoate | 3106 | ≤42 | ≥58 | OP7 | ||||||
tert-Butyl peroxy-3,5,5-trimethylhexanoate | UN3109 | ≤32 | ≥68 | OP8 | ||||||
3-Chloroperoxybenzoic acid | UN3102 | >57-86 | ≥14 | OP1 | ||||||
3-Chloroperoxybenzoic acid | UN3106 | ≤57 | ≥3 | ≥40 | OP7 | |||||
3-Chloroperoxybenzoic acid | UN3106 | ≤77 | ≥6 | ≥17 | OP7 | |||||
Cumyl hydroperoxide | UN3107 | >90-98 | ≤10 | OP8 | 13 | |||||
Cumyl hydroperoxide | UN3109 | ≤90 | ≥10 | OP8 | 13, 15 | |||||
Cumyl peroxyneodecanoate | 3115 | ≤87 | ≥13 | OP7 | −10 | 0 | ||||
Cumyl peroxyneodecanoate | UN3115 | ≤77 | ≥23 | OP7 | −10 | 0 | ||||
Cumyl peroxyneodecanoate [as a stable dispersion in water] | UN3119 | ≤52 | OP8 | −10 | 0 | |||||
Cumyl peroxyneoheptanoate | UN3115 | ≤77 | ≥23 | OP7 | −10 | 0 | ||||
Cumyl peroxypivalate | UN3115 | ≤77 | ≥23 | OP7 | −5 | 5 | ||||
Cyclohexanone peroxide(s) | UN3104 | ≤91 | ≥9 | OP6 | 13 | |||||
Cyclohexanone peroxide(s) | UN3105 | ≤72 | ≥28 | OP7 | 5 | |||||
Cyclohexanone peroxide(s) [as a paste] | UN3106 | ≤72 | OP7 | 5, 21 | ||||||
Cyclohexanone peroxide(s) | Exempt | ≤32 | >68 | Exempt | 29 | |||||
Diacetone alcohol peroxides | UN3115 | ≤57 | ≥26 | ≥8 | OP7 | 40 | 45 | 5 | ||
Diacetyl peroxide | UN3115 | ≤27 | ≥73 | OP7 | 20 | 25 | 8,13 | |||
Di-tert-amyl peroxide | UN3107 | ≤100 | OP8 | |||||||
2,2-Di-(tert-amylperoxy)-butane | 3105 | ≤57 | ≥43 | OP7 | ||||||
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1,1-Di-(tert-amylperoxy)cyclohexane | UN3103 | ≤82 | ≥18 | OP6 | ||||||
Dibenzoyl peroxide | UN3102 | >51-100 | ≤48 | OP2 | 3 | |||||
Dibenzoyl peroxide | UN3102 | >77-94 | ≥6 | OP4 | 3 | |||||
Dibenzoyl peroxide | UN3104 | ≤77 | ≥23 | OP6 | ||||||
Dibenzoyl peroxide | UN3106 | ≤62 | ≥28 | ≥10 | OP7 | |||||
Dibenzoyl peroxide [as a paste] | UN3106 | >52-62 | OP7 | 21 | ||||||
Dibenzoyl peroxide | UN3106 | >35-52 | ≥48 | OP7 | ||||||
Dibenzoyl peroxide | UN3107 | >36-42 | ≥18 | ≤40 | OP8 | |||||
Dibenzoyl peroxide [as a paste] | UN3108 | ≤56.5 | ≥15 | OP8 | ||||||
Dibenzoyl peroxide [as a paste] | UN3108 | ≤52 | OP8 | 21 | ||||||
Dibenzoyl peroxide [as a stable dispersion in water] | UN3109 | ≤42 | OP8 | |||||||
Dibenzoyl peroxide | Exempt | ≤35 | ≥65 | Exempt | 29 | |||||
Di-(4-tert-butylcyclohexyl)peroxydicarbonate | UN3114 | ≤100 | OP6 | 30 | 35 | |||||
Di-(4-tert-butylcyclohexyl)peroxydicarbonate [as a stable dispersion in water] | UN3119 | ≤42 | OP8 | 30 | 35 | |||||
Di-tert-butyl peroxide | UN3107 | >52-100 | OP8 | |||||||
Di-tert-butyl peroxide | UN3109 | ≤52 | ≥48 | OP8 | 24 | |||||
Di-tert-butyl peroxyazelate | UN3105 | ≤52 | ≥48 | OP7 | ||||||
2,2-Di-(tert-butylperoxy)butane | UN3103 |